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Borate sulfide - Wikipedia

From Wikipedia, the free encyclopedia

Borate sulfides are chemical mixed anion compounds that contain any kind of borate and sulfide ions. They are distinct from thioborates in which sulfur atoms replace oxygen in borates. There are also analogous borate selenides, with selenium ions instead of sulfur.

List

name	chem	mw	crystal system	space group	unit cell	volume	density	comments	references
	Zn₄B₆O₁₂S			I43m				NLO 1.9 × KDP	^[1]
cadmium sulfur boracite	Cd₃B₇O₁₃S₂		cubic	F43c					^[2]
	La₆Nb₂MgSB₈O₂₆		trigonal	P3	a=8.2137 c =8.8601			clear	^[3]
	Ce₆Nb₂MgSB₈O₂₆		trigonal	P3	a=8.1672 c=8.8093			clear	^[3]
	Pr₆Nb₂MgSB₈O₂₆		trigonal	P3	a=8.1362 c=8.7716			yellowish green	^[3]
	Nd₆Nb₂MgSB₈O₂₆		trigonal	P3	a=8.1135 c=8.7469			clear	^[3]
EBOS	Eu₂B₅O₉S	534.03	orthorhombic	Pnn2	a=11.2909 b=11.3742 c=6.4440 Z=4	827.57	4.286	black	^[4]
EBOSI	Eu_4.5(B₅O₉)₂SI	1238.88	orthorhombic	Pnn2	a=11.529 b=11.550 c=6.5070 Z=2	866.5	4.748	yellow-green band gap 1.98 eV	^[4]
EMSBO	Eu₉MgS₂B₂₀O₄₁	2328.27	Hexagonal	P6₃/m	a=8.2708 c=24.919 Z=2	1476.3	5.238	brown	^[5]
	Eu₆Ta₂MgSB₈O₂₆	1832.51	trigonal	P3	a=8.0431 c=8.6486 Z=1	484.53	6.280		^[6]
	Sm₃S₃BO₃	606.04	triclinic	P1	a=4.0173 b=7.647 c=11.241 α=91.339 β=91.275 γ=90.349 Z=2	345.14	5.832	green; band gap 2.5 eV	^[7]
	Gd₃S₃BO₃	626.74	triclinic	P1	a=3.9725 b=7.5945 c=11.182 α=91.402 β=91.093 γ=90.206 Z=2	337.30	6.173	pale yellow; band gap 2.65 eV	^[8]

References

^ Zhou, Wenfeng; Yao, Wen-Dong; Tang, Ru-Ling; Xue, Huaiguo; Guo, Sheng-Ping (2021-06-25). "Second-order nonlinear optical and photoelectric properties of Zn4B6O12S". Journal of Alloys and Compounds. 867: 158879. doi:10.1016/j.jallcom.2021.158879. ISSN 0925-8388. S2CID 233544941.
^ Gould, R O; Nelmes, R J; Gould, S E B (1981-12-10). "Structural studies of boracites. VII. Cadmium sulphur boracite at room temperature". Journal of Physics C: Solid State Physics. 14 (34): 5259–5267. Bibcode:1981JPhC...14.5259G. doi:10.1088/0022-3719/14/34/008. ISSN 0022-3719.
^ ^a ^b ^c ^d Tang, Ru-Ling; Wei, Yu-Long; Chi, Yang; Shi, Zhi-Hui; Liu, Wenlong; Guo, Sheng-Ping (2022-06-13). "Cation Regulation to Investigate the Chalcogenide Borate RE 6 Nb 2 MgSB 8 O 26 (RE = La–Nd) Family". Inorganic Chemistry. 61 (23): 8653–8661. doi:10.1021/acs.inorgchem.2c00033. ISSN 0020-1669. PMID 35622004. S2CID 249095609.
^ ^a ^b Chi, Yang; Xue, Huai-Guo; Guo, Sheng-Ping (2020-01-21). "Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material". Inorganic Chemistry. 59 (2): 1547–1555. doi:10.1021/acs.inorgchem.9b03426. ISSN 0020-1669. PMID 31909601. S2CID 210043683.
^ Chi, Yang; Xu, Jing; Xue, Huai-Guo; Zhang, Yueping; Chen, Xiaolong; Whangbo, Myung-Hwan; Guo, Sheng-Ping; Deng, Shuiquan (2019-06-19). "Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu9MgS2B20O41". Journal of the American Chemical Society. 141 (24): 9533–9536. doi:10.1021/jacs.9b04627. ISSN 0002-7863. PMID 31184141. S2CID 184485492.
^ Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster". Inorganic Chemistry. 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN 0020-1669. PMID 32090554. S2CID 211263182.
^ Guo, Sheng-Ping; Chi, Yang; Xue, Huai-Guo (2015-12-07). "Sm 3 S 3 BO 3 : The First Sulfide Borate without S–O and B–S Bonds". Inorganic Chemistry. 54 (23): 11052–11054. doi:10.1021/acs.inorgchem.5b01930. ISSN 0020-1669. PMID 26558599.
^ Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01). "Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)". New Journal of Chemistry. 40 (8): 6720–6727. doi:10.1039/C6NJ00549G. ISSN 1369-9261.

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