Palladium(II) iodide

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Palladium(II) iodide - Wikipedia

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Palladium(II) iodide
Identifiers


CAS Number	7790-38-7^Y
3D model (JSmol)	Interactive image
ChemSpider	74228^Y
ECHA InfoCard	100.029.276
EC Number	232-203-7
PubChem CID	82251
CompTox Dashboard (EPA)	DTXSID90999090
InChI InChI=1S/2HI.Pd/h21H;/q;;+2/p-2^Y Key: HNNUTDROYPGBMR-UHFFFAOYSA-L^Y InChI=1/2HI.Pd/h21H;/q;;+2/p-2 Key: HNNUTDROYPGBMR-NUQVWONBAU
SMILES [Pd](I)I
Properties
Chemical formula	I₂Pd
Molar mass	360.229 g/mol
Appearance	Black crystals
Density	6,003 g/cm³
Melting point	350 °C (decomposes)
Solubility in water	Insoluble in water
Hazards
GHS labelling:^[1]
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Related compounds
Other anions	Palladium(II) fluoride Palladium(II) chloride Palladium(II) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references

Palladium(II) iodide is an inorganic compound of palladium and iodine. It is commercially available, though less common than palladium(II) chloride, the usual entry point to palladium chemistry. Three polymorphs are known.^[2]

Preparation

Palladium(II) iodide can be obtained by treating a dilute solution of palladium in nitric acid with sodium iodide at 80 °C.^[2]

The high-temperature polymorph α-palladium(II) iodide can be produced by reaction of the elements at temperature above 600 °C. The γ-modification is produced as an almost amorphous powder by addition of iodide salts to aqueous H₂PdCl₄ solution . When heated in dilute hydrogen iodide solution, this polymorph transforms into the β phase at around 140 °C.^[3]

Reactions and uses

Palladium(II) iodide is insoluble in water. It reacts with iodide giving PdI₄²⁻ anion:

PdI₂ + 2I⁻ → PdI2−4

It finds use as a catalyst.^[4]

Historically, the quantity of palladium in a solution may be determined gravimetrically by precipitation as palladium(II) iodide.^[5]

Crystallography

Palladium(II) iodide is an almost X-ray amorphous black powder. The α-modification has an orthorhombic crystal structure with the space group Pnmn(space group no. 58, position 5).^[6]

References

^ "C&L Inventory". echa.europa.eu. Retrieved 13 December 2021.
^ ^a ^b Handbuch der präparativen anorganischen Chemie. 3 (3., umgearb. Aufl ed.). Stuttgart: Enke. 1981. ISBN 978-3-432-87823-2.
^ Brendel, Kristin; Thiele, Gerhard (2001). "Binäre und Ternäre Verbindungen der Platinmetalle Palladium und Rhodium mit Tellur und Halogenen. Präparationen und strukturelle Charakterisierung". {{cite journal}}: Cite journal requires |journal= (help)
^ Gabriele, Bartolo; Salerno, Giuseppe (2006), "Palladium(II) Iodide", Encyclopedia of Reagents for Organic Synthesis, American Cancer Society, doi:10.1002/047084289x.rn00658, ISBN 978-0-470-84289-8, retrieved 2021-03-26
^ Beamish, F. E.; Dale, J. (1938). "Determination of Palladium by Means of Potassium Iodide". Industrial & Engineering Chemistry Analytical Edition. 10 (12): 697. doi:10.1021/ac50128a015.
^ Ans, Jean d'; Lax, Ellen (1998). Taschenbuch für Chemiker und Physiker (in German). Springer. ISBN 978-3-540-60035-0.