Platinum(II) bis(acetylacetonate)

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Platinum(II) bis(acetylacetonate) - Wikipedia

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Platinum(II) bis(acetylacetonate)
Names



Other names Bis(2,4-pentanedionato)platinum; Platinum bis(acetylacetonate); Bis(acetylacetonato)platinum
Identifiers
CAS Number	15170-57-7^Y
3D model (JSmol)	coordination form: Interactive image ionic form: Interactive image
ChemSpider	4588258
ECHA InfoCard	100.035.642
EC Number	239-223-5
PubChem CID	10960186
InChI InChI=1S/2C5H8O2.Pt/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/b2*4-3-; Key: VEJOYRPGKZZTJW-FDGPNNRMSA-N
SMILES coordination form: CC(=C[C-](C)O1)O[Pt+2]12OC(=C[C-](C)O2)C ionic form: O=C(C)/C=C(C)\[O-].O=C(C)/C=C(C)\[O-].[Pt+2]
Properties
Chemical formula	C₁₀H₁₄O₄Pt
Molar mass	393.302 g·mol⁻¹
Appearance	yellow solid
Density	2.362 g/cm³
Melting point	239.4 C (dec.)^[1]
Solubility in water	insoluble
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302, H312, H315, H319, H332, H335, H361
Precautionary statements	P201, P202, P261, P264, P270, P271, P280, P281, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P308+P313, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Platinum(II) bis(acetylacetonate) is the coordination compound with the formula Pt(O₂C₅H₇)₂, abbreviated Pt(acac)₂. The homoleptic acetylacetonate complex of platinum(II), it is a yellow, benzene-soluble solid. According to X-ray crystallography, the Pt center is square planar.^[2] The compound is a widely used precursor to platinum-based catalysts.^[3]

The complex is prepared by the reaction of the platinum(II) aquo complex [Pt(H₂O)₄]²⁺ with acetylacetone.^[4]

References

^ Flanagan, Scott; Hall, Eric; Bowie, Wade; Fuhs, James W.; Logan, Robbie; Maniei, Farzaneh; Hunt, Andrew (2005). "A design-of-experiments approach to modeling activity coefficients in solvent mixtures: a case study using platinum(ii) acetylacetonate in mixtures of acetone, cyclohexanol, 1,2,3,4-tetrahydronaphthalene and propylene carbonate". Green Chemistry. 7 (5): 333. doi:10.1039/b418130a. ISSN 1463-9262.
^ Ha, Kwang (2011). "Crystal Structure of Bis(pentane-2,4-dionato)κ²O,O')platinum(II), Pt(C₅H₇O₂)₂". Zeitschrift für Kristallographie - New Crystal Structures. 226 (3). doi:10.1524/ncrs.2011.0147.
^ Xiaoqing Huang; Zipeng Zhao; Liang Cao; Yu Chen; Enbo Zhu; Zhaoyang Lin; Mufan Li; Aiming Yan; Alex Zettl; Y. Morris Wang; Xiangfeng Duan; Tim Mueller; Yu Huang (2015). "High-Performance Transition Metal-Doped Pt₃Ni Octahedra for Oxygen Reduction Reaction". Science. 348 (6240): 1230–1234. Bibcode:2015Sci...348.1230H. doi:10.1126/science.aaa8765. PMID 26068847.
^ Okeya, Seichi; Kawaguchi, Shinichi (1980). "The bis(β-Diketonato)Platinum(II) Complexes". The Bis(β‐diketonato)Platinum(II)Complexes. Inorganic Syntheses. Vol. 20. pp. 65–67. doi:10.1002/9780470132517.ch20. ISBN 9780470132517.

Pt(−II)

Pt(0)

Pt(II)

Organoplatinum(II) compounds	PtCl₂(Cod) Pt(CNO)₂ KPtCl₃C₂H₄

Pt(IV)

Pt(V)

Pt(VI)

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