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  3. Push–pull olefin - Wikipedia
Push–pull olefin - Wikipedia
From Wikipedia, the free encyclopedia
(Redirected from Push-pull olefin)
For other uses of "push-pull", see Push-pull (disambiguation).

A push-pull olefin is a type of olefin characterized by an electron-withdrawing substituent on one side of the double bond and an electron-donating substituent on the other side. This makes the pi bond very polarized. The rotational barrier for a push-pull olefin is lower than that of an ordinary olefin and this makes it an interesting candidate for a molecular switch, for instance azobenzenes. A push-pull configuration also helps to stabilize the double bond because the carbon-carbon bond has considerably less double bond character. For instance, cyclobutadiene is a very unstable molecule but with both olefinic bonds in push-pull configuration (two ester substituents and two tertiary amine substituents) the molecule is stable indeed.

References

  • Ethyl (2-cyano-3-ethoxyacryloyl)carbamate: irreversible thermal isomerization of a push-pull olefin Kuangsen Sung, Ming-Chi Lin, Pin-Mei Huang, Bo-Ren Zhuang, Robert Sung, Ru-Rong Wu Arkivoc 2005 p. 131 [1] open access publication

See also

Sunting pranala
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