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- [6+4] Cycloaddition is a type of cycloaddition between a six-atom pi system and a four-atom pi system, leading to a ten-membered ring. Because this is...9 KB (1,075 words) - 20:53, 22 July 2024
- Other cycloaddition reactions exist: (4+3) cycloadditions, [6+4] cycloadditions, [2 + 2] photocycloadditions, metal-centered cycloaddition and [4+4] photocycloadditions...12 KB (1,317 words) - 23:37, 6 December 2024
- A (4+3) cycloaddition is a cycloaddition between a four-atom π-system and a three-atom π-system to form a seven-membered ring. Allyl or oxyallyl cations...10 KB (1,268 words) - 11:59, 1 December 2024
- Ketene cycloadditions are the reactions of the pi system of ketenes with unsaturated compounds to provide four-membered or larger rings. [2+2], [3+2],...9 KB (1,180 words) - 00:32, 24 August 2024
- The azide-alkyne Huisgen cycloaddition is a 1,3-dipolar cycloaddition between an azide and a terminal or internal alkyne to give a 1,2,3-triazole. Rolf...21 KB (2,639 words) - 20:31, 22 July 2024
- cycloaddition is a chemical reaction between a 1,3-dipole and a dipolarophile to form a five-membered ring. The earliest 1,3-dipolar cycloadditions were...65 KB (6,396 words) - 21:04, 1 August 2024
- Woodward–Hoffmann rules (redirect from 2+2 Cycloaddition)formidable (up to ca. 5 eV or 480 kJ/mol in the case of a forbidden [2+2] cycloaddition), the prohibition is not absolute, and symmetry-forbidden reactions...93 KB (11,920 words) - 14:03, 12 December 2024
- Diels-Alder reaction and inverse electron demand Diels-Alder reaction [4+1] cycloadditions between isonitriles (isocyanides) and tetrazines nucleophilic substitution...48 KB (5,450 words) - 06:03, 4 January 2025
- A metal-centered cycloaddition is a subtype of the more general class of cycloaddition reactions. In such reactions "two or more unsaturated molecules...10 KB (1,034 words) - 02:09, 2 August 2024
- The [4+4] Photocycloaddition is a cycloaddition reaction in which two unsaturated molecules connect via four atoms from each molecule (hence "4 + 4") to...8 KB (917 words) - 11:57, 13 August 2023
- Bioorthogonal chemistry (section [4+1] Cycloaddition)fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry)...44 KB (5,098 words) - 11:34, 22 December 2024
- 4-chlorophenyl azide are important in click chemistry. The azide reacts in a cycloaddition with alkyl-nitriles to form 1,2,3-triazoles. The use of azides is very...7 KB (566 words) - 21:19, 8 February 2025
- Nitroethylene (section Cycloaddition)and their derivatives in a [4+2] cycloaddition. Nitroethene can react at the 2π electron source in a [3+2] cycloaddition with nitrones. Nitroethylene...8 KB (846 words) - 13:37, 13 July 2024
- Vinylcyclopropane (5+2) cycloaddition is a type of cycloaddition between a vinylcyclopropane (VCP) and an olefin or alkyne to form a seven-membered ring...15 KB (1,523 words) - 02:17, 15 November 2024
- In organic chemistry, enone–alkene cycloadditions are a version of the [2+2] cycloaddition. This reaction involves an enone and alkene as substrates....9 KB (1,024 words) - 15:05, 11 February 2025
- allows for quantitative, regioselective formal Huisgen 1,3-dipolar cycloadditions between alkynes and azides, in a variety of aqueous and organic solvents...4 KB (279 words) - 02:00, 22 August 2022
- Diels–Alder reaction (redirect from Diels-Alder cycloaddition reaction)mechanism. More specifically, it is classified as a thermally allowed [4+2] cycloaddition with Woodward–Hoffmann symbol [π4s + π2s]. It was first described...69 KB (7,907 words) - 04:59, 11 February 2025
- Alkyne trimerisation (category Cycloadditions)An alkyne trimerisation is a [2+2+2] cycloaddition reaction in which three alkyne units (C≡C) react to form a benzene ring. The reaction requires a metal...18 KB (1,930 words) - 14:01, 11 February 2025
- Scheme 14. Gold-catalyzed formal intramolecular [4+2] cycloaddition of 1,6-enynes This formal cycloaddition was proposed to proceed via the cascade process...26 KB (2,852 words) - 01:12, 31 January 2025
- Thiazole (redirect from 5,5-dimethyl thiazolidinium-4-carboxylate)[2+2]cycloaddition to a cyclobutene, then to a 1,3-thiazepine in a 4-electron electrocyclic ring opening and then to a 7-thia-2-azanorcaradiene in a 6-electron...12 KB (1,151 words) - 11:33, 2 October 2024
- alkyl azides are readily reduced to primary amines, while 1,3 - dipolar cycloadditions of azide derivatives with dipolarophiles such as alkenes, alkynes, and
- alkene added is called dienophile. The reaction is also called a [4+2]cycloaddition. This type of reaction can still be carried out in the absence of